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Wavellite

Mineral

Al3(PO4)2(OH,F)3·5H2O

Also known as: Hydrous Aluminum Phosphate

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Description

Wavellite is a hydrated aluminum phosphate mineral, known for its distinctive radiating, spherical, or hemispherical aggregates of acicular (needle-like) crystals. These aggregates, often referred to as 'starbursts' or 'botryoidal' forms, can be quite beautiful and are highly prized by mineral collectors. Its color varies, commonly appearing in shades of green, yellow-green, white, colorless, brown, or black. It typically forms in low-temperature environments, often as a secondary mineral in metamorphic rocks or phosphate deposits.

How to Identify

Color
Typically green, yellow-green, white, colorless, brown, or black. Often translucent to opaque.
Luster
Vitreous (glassy) to pearly on cleavage surfaces.
Texture
Often forms radiating, spherical, or hemispherical aggregates of fine acicular crystals, giving a botryoidal or mammillary texture.
Crystal Form
Orthorhombic system. Crystals are typically acicular (needle-like) to prismatic, often forming characteristic radiating aggregates, spheres, or hemispheres. Individual crystals are rare and usually very small.
Cleavage
Good on {110} and {010}, but rarely observed due to the fine-grained, radiating habit.
Geological Environment
Found in low-temperature hydrothermal veins, in fissures and cavities of aluminous metamorphic rocks (e.g., phyllites, slates), and as a secondary mineral in phosphate-bearing igneous or sedimentary rocks. Often associated with limonite, variscite, crandallite, and other secondary phosphates.

Key Facts

  • Hardness: 3.5-4 on the Mohs scale
  • Specific Gravity: 2.30-2.37 g/cm³
  • Crystal System: Orthorhombic
  • Color: Green, yellow-green, white, colorless, brown, black
  • Luster: Vitreous to pearly
  • Transparency: Transparent to translucent to opaque
  • Fracture: Uneven to subconchoidal
  • Cleavage: Good on {110} and {010}, but rarely observed due to habit
  • Composition: Hydrated aluminum phosphate with hydroxyl and fluoride. Al3(PO4)2(OH,F)3·5H2O

Quick Check

  • Color: Green, yellow-green, white, colorless, brown, black
  • Luster: Vitreous to pearly
  • Streak: White

Physical Characteristics

  • Crystal Habit: Typically forms radiating, spherical, or hemispherical aggregates of acicular to prismatic crystals; also botryoidal, mammillary, stalactitic, or massive.
  • Cleavage Type: Good on {110} and {010}, but often obscured by the radiating habit.
  • Fracture Type: Uneven to subconchoidal.
  • Tenacity: Brittle.
  • Luster Type: Vitreous to pearly.

Formation

Wavellite is a secondary mineral, typically forming in low-temperature hydrothermal veins, in fissures and cavities of aluminous metamorphic rocks, or as a weathering product of phosphate-bearing igneous or sedimentary rocks. It often occurs in association with limonite, variscite, crandallite, and other secondary phosphate minerals. The presence of aluminum, phosphate, and water, along with a slightly acidic to neutral pH, are crucial for its formation.

Usage

Wavellite has no significant industrial or commercial uses. It is primarily a mineral sought after by collectors for its aesthetic radiating crystal habits and attractive colors. Some specimens are cut and polished as cabochons, but its relative softness limits its use in jewelry.

Age Distribution

Wavellite forms in secondary environments, often associated with the weathering of phosphate-rich rocks or hydrothermal alteration. Its formation is not tied to a specific geological age but rather to the conditions present for its precipitation.

Where to Find

Montgomery County, Arkansas, USA

Famous for producing some of the finest wavellite specimens, often with vibrant green radiating spheres in novaculite.

Llallagua, Potosí, Bolivia

Known for excellent specimens, often associated with other phosphate minerals.

Devon, England

The type locality for wavellite, where it was first discovered.

Saxony, Germany

Produces good quality wavellite specimens.

Queensland, Australia

Occurrences in various localities, sometimes forming attractive green aggregates.

Finding Tips

Look for specific geological settings

Focus on areas with aluminous metamorphic rocks (slates, phyllites) or weathered phosphate-rich deposits. Check for evidence of hydrothermal alteration or secondary mineralization.

Examine cavities and fissures

Wavellite often forms in open spaces within rocks. Look for vugs, cracks, and fractures where crystals might have grown.

Identify associated minerals

Wavellite frequently occurs with limonite (iron oxides), variscite, crandallite, and other secondary phosphate minerals. The presence of these minerals can be an indicator.

Observe crystal habit

The most distinctive feature is its radiating, spherical, or hemispherical aggregates. These 'starburst' patterns are a strong indicator. Use a hand lens to observe the acicular crystals.

Consider color and luster

While variable, the characteristic green to yellow-green color and vitreous to pearly luster can help in identification.

Similar Rocks

Variscite

Variscite

Also known as: Aluminum Phosphate

Turquoise

Turquoise

Also known as: Hydrated Copper Aluminum Phosphate

Crandallite

Crandallite

Also known as: Calcium Aluminum Phosphate Hydroxide

Scientific Classification

Mineral Class
Phosphates
Group
Wavellite Group
Crystal System
Orthorhombic
Chemical Formula
Al3(PO4)2(OH,F)3·5H2O
Composition
Aluminum phosphate hydroxide fluoride hydrate. Contains Aluminum (Al), Phosphorus (P), Oxygen (O), Hydrogen (H), and Fluorine (F).

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