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Aragonite is a carbonate mineral, one of the two common naturally occurring crystal forms of calcium carbonate (CaCO3), the other being calcite. It crystallizes in the orthorhombic system, distinguishing it from calcite's trigonal system. Aragonite often forms in acicular (needle-like), columnar, fibrous, or radiating crystal habits. It can also occur in botryoidal, stalactitic, or coralloidal (e.g., 'Flos Ferri') forms. Its color is typically white, colorless, or gray, but can also be yellow, green, blue, or violet due to impurities. Aragonite is metastable at standard temperature and pressure and tends to alter to calcite over geological time, a process that can be accelerated by heat and water. This transformation is a key factor in the preservation of fossils, as aragonitic shells often recrystallize to calcite.
How to Identify
- Color
- Typically white, colorless, or gray. Can also be yellow, green, blue, violet, or brown due to impurities.
- Luster
- Vitreous (glassy) to resinous.
- Texture
- Can be fibrous, columnar, granular, or massive. Often forms radiating aggregates or acicular crystals.
- Crystal Form
- Orthorhombic system. Commonly forms prismatic, acicular, or tabular crystals. Also found in botryoidal, stalactitic, and coralloidal (e.g., 'Flos Ferri') habits. Twinning is common, often forming pseudo-hexagonal prisms.
- Cleavage
- Distinct cleavage in one direction ({010}), poor in two others ({110} and {011}). Often difficult to observe due to fibrous or fine-grained habits.
- Geological Environment
- Found in sedimentary environments (e.g., marine and freshwater precipitates, ooids, shells), hydrothermal veins, hot springs, caves (speleothems), serpentinites, and as a component of some igneous rocks (e.g., carbonatites).
Key Facts
- Hardness: 3.5-4 (Mohs scale)
- Specific Gravity: 2.93-2.95 g/cm³
- Crystal System: Orthorhombic
- Color: White, colorless, gray, yellow, green, blue, violet, brown
- Luster: Vitreous to resinous
- Transparency: Transparent to translucent
- Fracture: Subconchoidal to uneven
- Cleavage: Distinct on {010}, poor on {110} and {011}
- Composition: Calcium Carbonate (CaCO3)
Quick Check
- Color: White, colorless, gray, yellow, green, blue, violet, brown
- Luster: Vitreous to resinous
- Streak: White
Physical Characteristics
- Crystal Habit: Prismatic, acicular, tabular, fibrous, columnar, radiating, botryoidal, stalactitic, coralloidal (Flos Ferri). Often twinned, forming pseudo-hexagonal prisms.
- Cleavage Type: Distinct in one direction ({010}), poor in two others ({110} and {011}).
- Fracture Type: Subconchoidal to uneven.
- Tenacity: Brittle.
- Luster Type: Vitreous (glassy) to resinous.
Formation
Aragonite is a polymorph of calcium carbonate (CaCO3), meaning it has the same chemical composition as calcite but a different crystal structure. It typically forms at lower temperatures and pressures than calcite, often in sedimentary and low-temperature metamorphic environments. Key formation conditions include: precipitation from marine and freshwater environments (e.g., in shells of marine organisms, ooids, speleothems), hydrothermal veins, hot springs, and as a component of some serpentinites. It is metastable at surface conditions and will slowly convert to calcite over geological time, especially in the presence of water.
Usage
Aragonite has limited industrial uses compared to calcite due to its relative scarcity and metastability. It is primarily used as a decorative stone, for carving, and as a collector's mineral. Biogenic aragonite is a significant component of coral reefs and mollusk shells. In some specialized applications, it is used in water treatment to remove heavy metals and in some pharmaceutical preparations. Its unique crystal habits make it a popular specimen for mineral collectors.
Age Distribution
Aragonite forms in various geological settings and is not restricted to a specific geological age. It can be found in modern and ancient environments.
Where to Find
Spain
Molina de Aragón, Guadalajara, Spain, is the type locality and known for excellent prismatic crystals.
Slovakia
Ochtinská Aragonite Cave, Slovakia, is famous for its unique aragonite formations, including 'aragonite flowers' (Flos Ferri).
Austria
Styria, Austria, is another classic locality for well-formed aragonite crystals.
United States
Various localities, including New Mexico (e.g., Santa Eulalia District), Arizona, and California, where it occurs in volcanic rocks, hot springs, and cave deposits.
Mexico
Santa Eulalia, Chihuahua, Mexico, produces fine aragonite specimens.
Italy
Sicily, Italy, is known for aragonite in sulfur deposits.
Finding Tips
Look in Caves and Hot Springs
Aragonite frequently forms in cave environments as speleothems (stalactites, stalagmites, 'cave flowers') and around hot springs due to rapid precipitation from supersaturated waters.
Examine Sedimentary Rocks
Check for aragonite in recent marine sediments, oolitic limestones, and the shells of modern marine organisms (e.g., mollusks, corals).
Hydrothermal Veins
Explore areas with hydrothermal activity, as aragonite can precipitate from low-temperature hydrothermal solutions.
Serpentinite Occurrences
Aragonite can be found in serpentinized ultramafic rocks, often associated with other carbonate minerals.
Acid Test
Like calcite, aragonite will effervesce vigorously in dilute hydrochloric acid (HCl). This distinguishes it from many other non-carbonate minerals. However, it does not distinguish it from calcite.
Hardness Test
Aragonite has a Mohs hardness of 3.5-4, which is slightly harder than calcite (3). This can be a subtle but useful distinguishing feature if a clean crystal face is available for testing.
Similar Rocks
Calcite
Calcite (CaCO3)
Also known as: Calcium Carbonate
Dolomite
Dolomite (CaMg(CO3)2)
Also known as: Calcium Magnesium Carbonate
Gypsum
Gypsum (CaSO4·2H2O)
Also known as: Hydrated Calcium Sulfate
Scientific Classification
- Mineral Class
- Carbonates
- Group
- Aragonite Group
- Crystal System
- Orthorhombic
- Chemical Formula
- CaCO3
- Composition
- Calcium Carbonate
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