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Uranophane

Mineral

Ca(UO2)2(SiO3OH)2·5H2O

Also known as: Uranophane-alpha, Uranophane-I

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Description

Uranophane is a hydrated calcium uranyl silicate mineral. It is one of the most common secondary uranium minerals and is characterized by its distinctive yellow to yellowish-green color and often fibrous or acicular crystal habit. It is strongly radioactive due to its high uranium content. Uranophane is typically found as coatings, crusts, or radiating aggregates in the oxidized zones of uranium deposits. It is a member of the uranophane group of minerals, which includes uranophane-beta (a dimorph) and other related uranyl silicates.

How to Identify

Color
Typically lemon-yellow to yellowish-green, sometimes straw-yellow or brownish-yellow. The color is often vibrant and characteristic.
Luster
Silky to vitreous, sometimes dull or earthy in massive forms.
Texture
Often fibrous, acicular (needle-like), or radiating aggregates. Can also be massive, earthy, or as powdery coatings.
Crystal Form
Monoclinic. Crystals are typically acicular to fibrous, elongated along [010], often forming radiating aggregates, tufts, or felted masses. Individual crystals are usually very small.
Cleavage
Perfect on {100}, good on {001}. This can be difficult to observe due to the small crystal size and fibrous habit.
Geological Environment
Oxidized zones of uranium ore deposits, particularly those associated with granitic or pegmatitic rocks, sandstones, or other host rocks containing primary uranium minerals. It forms as a secondary alteration product.

Key Facts

  • Hardness: 2.5-3 on the Mohs scale
  • Specific Gravity: 3.81-3.98 g/cm³
  • Crystal System: Monoclinic
  • Color: Lemon-yellow, yellowish-green, straw-yellow, brownish-yellow
  • Luster: Silky, vitreous, dull, earthy
  • Transparency: Transparent to translucent
  • Fracture: Uneven to splintery
  • Cleavage: Perfect on {100}, good on {001}
  • Composition: Hydrated Calcium Uranyl Silicate

Quick Check

  • Color: Yellow to yellowish-green
  • Luster: Silky to vitreous
  • Streak: Pale yellow to yellowish-white

Physical Characteristics

  • Crystal Habit: Acicular, fibrous, radiating aggregates, tufts, felted masses, coatings, crusts, massive, earthy, powdery.
  • Cleavage Type: Perfect basal cleavage on {100}, good cleavage on {001}. Often difficult to observe due to fine-grained nature.
  • Fracture Type: Uneven to splintery.
  • Tenacity: Brittle.
  • Luster Type: Silky to vitreous in crystalline forms; dull to earthy in massive or powdery forms.

Formation

Uranophane is a secondary uranium mineral, typically forming in the oxidized zones of uranium ore deposits. It results from the alteration of primary uranium minerals (like uraninite) in the presence of calcium-bearing solutions and silica. The alteration process involves the dissolution of primary uranium minerals, followed by the precipitation of uranophane under oxidizing and slightly acidic to neutral conditions. It often occurs as a coating or crust on other minerals, or as radiating aggregates in fractures and cavities.

Usage

Uranophane is primarily of scientific interest as an indicator mineral for uranium mineralization and as a subject of study in actinide geochemistry and environmental remediation. It is not used commercially due to its radioactivity and relatively low uranium content compared to primary ores. However, its presence can indicate the potential for economically viable uranium deposits nearby.

Age Distribution

Uranophane is a secondary mineral, forming from the alteration of primary uranium minerals. Its age is therefore dependent on the age of the primary uranium mineralization and the subsequent alteration events, which can span from Precambrian to recent.

Where to Find

Shinkolobwe Mine, Katanga, Democratic Republic of Congo

A classic locality for well-formed uranophane crystals and aggregates, often associated with other secondary uranium minerals.

Marysvale District, Piute County, Utah, USA

Known for significant occurrences of uranophane in various uranium deposits.

Joachimsthal (Jáchymov), Krušné Hory Mountains, Czech Republic

Historically important uranium mining district where uranophane is found.

Rössing Uranium Mine, Erongo Region, Namibia

A large open-pit uranium mine where uranophane occurs as a secondary mineral.

Various localities in France (e.g., Limousin, Morvan)

Uranophane is found in numerous uranium occurrences in the Hercynian massifs of France.

Finding Tips

Geiger Counter/Scintillometer

Due to its strong radioactivity, a Geiger counter or scintillometer is the most effective tool for locating uranophane in the field. Look for areas with elevated radiation readings.

Associated Minerals

Uranophane often occurs with other secondary uranium minerals such as autunite, torbernite, carnotite, and gummite, as well as primary uraninite. Look for these associations.

Oxidized Zones

Focus your search on the oxidized zones of known or suspected uranium deposits, particularly in fractures, vugs, and on the surfaces of other minerals.

Color and Habit

Visually identify its characteristic yellow to yellowish-green color and fibrous or radiating crystal habit. It often forms crusts or coatings on rock surfaces.

Safety Precautions

Always prioritize safety when searching for radioactive minerals. Wear appropriate personal protective equipment (gloves, mask), minimize direct handling, and avoid inhaling dust. Do not collect or store large quantities without proper shielding and disposal knowledge.

Similar Rocks

Soddyite

(UO2)2SiO4·2H2O

Also known as: None

Beta-Uranophane

Ca(UO2)2(SiO3OH)2·5H2O

Also known as: Uranophane-beta, Uranophane-II

Kasolite

Pb(UO2)SiO4·H2O

Also known as: None

Cuprosklodowskite

Cu(UO2)2(SiO3OH)2·6H2O

Also known as: None

Scientific Classification

Mineral Class
Silicates (Nesosilicates, specifically Uranyl Silicates)
Group
Uranophane Group
Crystal System
Monoclinic
Chemical Formula
Ca(UO2)2(SiO3OH)2·5H2O
Composition
Calcium (Ca), Uranium (U), Oxygen (O), Silicon (Si), Hydrogen (H). Contains approximately 56.8% UO3, 6.3% CaO, 14.2% SiO2, and 12.7% H2O.

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