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Peacock Ore (when tarnished)

Mineral assemblage

CuFeS2 (Chalcopyrite) and Cu5FeS4 (Bornite)

Also known as: Copper Pyrites (Chalcopyrite), Peacock Ore (Bornite)

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Description

Chalcopyrite with Bornite refers to an assemblage of these two distinct copper-iron sulfide minerals. Chalcopyrite is a brassy yellow mineral with a metallic luster, often tarnishing to iridescent blues, purples, and reds. Bornite, when freshly broken, is a reddish-brown to copper-red, but it rapidly tarnishes upon exposure to air, developing a characteristic iridescent blue, purple, and red sheen, which gives it the common name 'Peacock Ore'. This tarnish is due to the formation of thin oxide films on the surface. The two minerals can occur intimately intergrown, as exsolution lamellae, or as distinct grains within the same ore body. Their presence together signifies a significant copper mineralization.

How to Identify

Color
Chalcopyrite: Brassy yellow, often with iridescent tarnish (blue, purple, red). Bornite: Freshly broken, reddish-brown to copper-red; rapidly tarnishes to iridescent blue, purple, and red ('Peacock Ore').
Luster
Metallic.
Texture
Typically massive, granular, or disseminated. Can also form in veins or as coatings.
Crystal Form
Chalcopyrite: Tetragonal, often forming pseudotetrahedral or disphenoidal crystals, but commonly massive. Bornite: Orthorhombic (pseudocubic), typically massive, granular, or as disseminated grains. Less commonly forms distinct crystals.
Cleavage
Chalcopyrite: Poor, indistinct {011} cleavage. Bornite: Poor, indistinct {111} cleavage.
Geological Environment
Hydrothermal veins, porphyry copper deposits, volcanogenic massive sulfide (VMS) deposits, skarn deposits, contact metamorphic deposits, and sedimentary copper deposits.

Key Facts

  • Hardness: Chalcopyrite: 3.5-4 (Mohs). Bornite: 3 (Mohs).
  • Specific Gravity: Chalcopyrite: 4.1-4.3. Bornite: 4.9-5.3.
  • Crystal System: Chalcopyrite: Tetragonal. Bornite: Orthorhombic (pseudocubic).
  • Color: Chalcopyrite: Brassy yellow, often tarnished. Bornite: Reddish-brown to copper-red, rapidly tarnishing iridescent.
  • Luster: Metallic.
  • Transparency: Opaque.
  • Fracture: Chalcopyrite: Uneven to conchoidal. Bornite: Uneven to subconchoidal.
  • Cleavage: Chalcopyrite: Poor, indistinct {011}. Bornite: Poor, indistinct {111}.
  • Composition: Chalcopyrite: Copper iron sulfide (CuFeS2). Bornite: Copper iron sulfide (Cu5FeS4).

Quick Check

  • Color: Chalcopyrite: Brassy yellow, often tarnished iridescent. Bornite: Reddish-brown (fresh), rapidly tarnishing to iridescent blue, purple, red.
  • Luster: Metallic.
  • Streak: Chalcopyrite: Greenish-black. Bornite: Grayish-black.

Physical Characteristics

  • Crystal Habit: Chalcopyrite: Commonly massive, disseminated, or in pseudotetrahedral crystals. Bornite: Commonly massive, granular, disseminated, or as exsolution lamellae within chalcopyrite.
  • Cleavage Type: Poor/Indistinct.
  • Fracture Type: Uneven to subconchoidal.
  • Tenacity: Brittle.
  • Luster Type: Metallic.

Formation

Chalcopyrite and Bornite commonly form together in a variety of ore-forming environments. They are primary copper-iron sulfide minerals. Chalcopyrite is typically the more abundant primary copper mineral in many porphyry copper deposits, volcanogenic massive sulfide (VMS) deposits, and skarn deposits. Bornite often forms in similar environments, frequently as a later-stage mineral or through exsolution from chalcopyrite at lower temperatures. They can also occur in hydrothermal veins, contact metamorphic deposits, and sedimentary copper deposits (e.g., Kupferschiefer type). The association often indicates a copper-rich, iron-sulfide-bearing environment.

Usage

Both chalcopyrite and bornite are primary ore minerals for copper, which is essential for electrical wiring, plumbing, construction, and various alloys. Bornite, due to its higher copper content (approximately 63.3% by weight) compared to chalcopyrite (approximately 34.6% by weight), is a particularly valuable copper ore. The aesthetic appeal of tarnished bornite (often sold as 'Peacock Ore') also makes it popular for ornamental purposes and mineral collecting.

Age Distribution

Found in deposits ranging from Precambrian to Cenozoic, often associated with major orogenic events and magmatic activity.

Where to Find

Bingham Canyon Mine, Utah, USA

One of the largest open-pit mines in the world, a classic porphyry copper deposit with abundant chalcopyrite and bornite.

Butte, Montana, USA

Historically significant copper mining district, known for its rich vein deposits containing chalcopyrite and bornite.

Cornwall, England

Historic mining region with numerous copper-tin lodes, where chalcopyrite and bornite are common.

Kupferschiefer deposits, Poland/Germany

World-class sedimentary copper deposits where bornite and chalcopyrite are major ore minerals.

Chuquicamata, Chile

Another massive porphyry copper deposit, rich in chalcopyrite and bornite.

Finding Tips

Look for Metallic Luster

Both minerals exhibit a distinct metallic luster, even when tarnished. This is a key indicator for sulfide minerals.

Observe Color and Tarnish

The brassy yellow of chalcopyrite and the rapid, iridescent tarnish of bornite are highly diagnostic. Freshly broken bornite will show a reddish-brown color before tarnishing.

Check for Associated Minerals

These minerals often occur with other sulfides like pyrite, sphalerite, and galena, as well as quartz, calcite, and various silicates in their host rocks.

Consider Geological Context

Focus on areas known for copper mineralization, such as hydrothermal alteration zones, porphyry intrusions, or VMS deposits.

Hardness Test

Chalcopyrite (3.5-4) and Bornite (3) are relatively soft and can be scratched by a steel knife, distinguishing them from harder minerals like pyrite (6-6.5).

Similar Rocks

Pyrite

FeS2

Also known as: Fool's Gold

Marcasite

FeS2

Also known as: White Iron Pyrites

Cubanite

CuFe2S3

Also known as: None

Covellite

CuS

Also known as: Indigo Copper

Scientific Classification

Mineral Class
Sulfides.
Group
Chalcopyrite Group (for Chalcopyrite), Bornite Group (for Bornite).
Crystal System
Chalcopyrite: Tetragonal. Bornite: Orthorhombic (pseudocubic).
Chemical Formula
Chalcopyrite: CuFeS2. Bornite: Cu5FeS4.
Composition
Chalcopyrite: Copper (34.6%), Iron (30.4%), Sulfur (35.0%). Bornite: Copper (63.3%), Iron (11.2%), Sulfur (25.5%).

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