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Iron Ore

Sedimentary (often), Metamorphic (BIFs), or Hydrothermal

Hematite or Goethite (likely concretions or nodules)

Also known as: Hematite, Goethite, Limonite (for mixtures of hydrous iron oxides), Bog Iron, Ironstone

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Description

Iron ore refers to rocks and minerals from which metallic iron can be economically extracted. The most important iron ore minerals are hematite (Fe2O3) and goethite (FeO(OH)). Hematite is an anhydrous iron oxide, while goethite is a hydrous iron oxide. These minerals often occur together, especially in weathered deposits. Concretions and nodules of iron ore are common, forming through the precipitation of iron oxides around a nucleus in sedimentary environments. These can range from small, pea-sized ooids to large, irregular masses. High-grade iron ores are typically rich in hematite, while lower-grade ores often contain significant goethite and other iron hydroxides, sometimes collectively referred to as limonite.

How to Identify

Color
Hematite: Steel-gray to black (specular hematite), reddish-brown to red (earthy hematite). Goethite: Yellowish-brown to dark brown, sometimes black.
Luster
Hematite: Metallic to dull/earthy. Goethite: Adamantine to dull/earthy.
Texture
Hematite: Can be massive, botryoidal, reniform, micaceous (specularite), or earthy. Goethite: Often fibrous, botryoidal, stalactitic, or earthy, commonly forming concretions and nodules.
Crystal Form
Hematite: Rhombohedral crystals, tabular, massive, botryoidal. Goethite: Orthorhombic crystals, but typically massive, fibrous, or botryoidal.
Cleavage
Hematite: No true cleavage, but parting along rhombohedral planes can occur. Goethite: Perfect cleavage on {010}, but rarely observed in massive forms.
Geological Environment
Hematite: Found in Banded Iron Formations (BIFs), hydrothermal veins, contact metamorphic deposits, and as a weathering product. Goethite: Common in lateritic soils, bog iron deposits, gossans (weathered sulfide deposits), and as concretions in sedimentary rocks.

Key Facts

  • Hardness: Hematite: 5-6.5 on Mohs scale; Goethite: 5-5.5 on Mohs scale
  • Specific Gravity: Hematite: 5.26; Goethite: 3.3-4.3
  • Crystal System: Hematite: Trigonal; Goethite: Orthorhombic
  • Color: Hematite: Steel-gray, black, reddish-brown, red; Goethite: Yellowish-brown, dark brown, black
  • Luster: Hematite: Metallic, submetallic, dull, earthy; Goethite: Adamantine, silky, dull, earthy
  • Transparency: Opaque
  • Fracture: Hematite: Uneven to subconchoidal; Goethite: Uneven
  • Cleavage: Hematite: None (parting common); Goethite: Perfect on {010} (rarely observed)
  • Composition: Hematite: Iron(III) oxide (Fe2O3); Goethite: Iron(III) oxyhydroxide (FeO(OH))

Quick Check

  • Color: Hematite: Steel-gray to red; Goethite: Yellowish-brown to dark brown
  • Luster: Hematite: Metallic to dull/earthy; Goethite: Adamantine to dull/earthy
  • Streak: Hematite: Reddish-brown; Goethite: Yellowish-brown

Physical Characteristics

  • Crystal Habit: Hematite: Rhombohedral, tabular, massive, botryoidal, reniform, micaceous (specularite), earthy. Goethite: Prismatic, acicular, fibrous, botryoidal, stalactitic, massive, earthy, oolitic, concretionary.
  • Cleavage Type: Hematite: None, but parting on {1011} is common. Goethite: Perfect on {010}, but often not visible in massive forms.
  • Fracture Type: Hematite: Uneven to subconchoidal. Goethite: Uneven.
  • Tenacity: Brittle
  • Luster Type: Hematite: Metallic, submetallic, dull, earthy. Goethite: Adamantine, silky, dull, earthy.

Formation

Iron ores, particularly those composed of hematite and goethite, form through a variety of geological processes. Banded Iron Formations (BIFs), the largest source of iron ore, are Precambrian sedimentary rocks formed by the precipitation of iron oxides and silica from ancient oceans, likely due to the oxygenation of the atmosphere by photosynthetic organisms. Later enrichment of BIFs through supergene processes (weathering and leaching) can form high-grade hematite deposits. Goethite and other hydrous iron oxides often form in surficial environments through the weathering of iron-bearing minerals, accumulating as concretions, nodules, or bog iron deposits in swamps and shallow marine settings. Hydrothermal processes can also deposit iron oxides.

Usage

Primarily used for the production of iron and steel, which are fundamental to construction, manufacturing, infrastructure, and transportation. Other uses include pigments (ochre), heavy media separation, and as a polishing agent (rouge).

Age Distribution

Precambrian to Cenozoic, with major deposits in the Precambrian (BIFs)

Where to Find

Pilbara Region, Western Australia

One of the world's largest iron ore provinces, dominated by high-grade hematite deposits derived from enriched BIFs.

Minas Gerais, Brazil

Significant deposits of high-grade hematite (itabirite) and goethite, often associated with BIFs.

Lake Superior Region, USA and Canada

Historically and currently a major source of iron ore, primarily from BIFs (e.g., Mesabi Range).

Krivoy Rog, Ukraine

Large deposits of high-grade hematite and magnetite associated with Precambrian BIFs.

Mauritania

Significant iron ore deposits, including hematite and goethite, often in BIFs.

Finding Tips

Look for Reddish Stains

Iron oxides, especially hematite, will often stain surrounding rocks and soil a distinctive reddish-brown color. This can be a good indicator of iron ore presence.

Check for Density

Iron ore minerals are relatively dense. Picking up a sample and feeling its weight can help distinguish it from lighter, non-ore minerals.

Perform a Streak Test

Hematite produces a characteristic reddish-brown streak, while goethite produces a yellowish-brown streak. This is a crucial diagnostic test.

Examine Concretions and Nodules

In sedimentary environments, look for rounded to irregular, often heavy, dark brown to black concretions or nodules, which are frequently composed of goethite or hematite.

Use a Magnet (for Magnetite, but also for weakly magnetic hematite)

While hematite and goethite are generally not strongly magnetic, some varieties of hematite can be weakly magnetic. Magnetite (Fe3O4), often associated with iron ore, is strongly magnetic and will readily attract a magnet.

Similar Rocks

Magnetite

Fe3O4

Also known as: Lodestone

Siderite

FeCO3

Also known as: Iron Carbonate

Pyrite

FeS2

Also known as: Fool's Gold

Scientific Classification

Mineral Class
Oxides (Hematite), Hydroxides (Goethite)
Group
Hematite Group (Hematite), Diaspore Group (Goethite)
Crystal System
Trigonal (Hematite), Orthorhombic (Goethite)
Chemical Formula
Fe2O3 (Hematite), FeO(OH) (Goethite)
Composition
Hematite: 69.9% Iron, 30.1% Oxygen. Goethite: 62.9% Iron, 27.0% Oxygen, 10.1% Hydrogen.

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