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How to identify Limonite pseudomorph after Pyrite

Limonite (Fe2O3·nH2O) pseudomorph after Pyrite (FeS2)

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To correctly identify Limonite pseudomorph after Pyrite (Limonite (Fe2O3·nH2O) pseudomorph after Pyrite (FeS2)), check each of these features in order. Many rocks and minerals look alike, so cross-reference multiple properties before deciding.

Step-by-step identification

  1. 1

    Color

    Overall color and any zoning or banding

    Typically yellowish-brown, reddish-brown, dark brown, or blackish-brown. The color is often dull and earthy.

  2. 2

    Luster

    How the surface reflects light: metallic, vitreous, dull

    Earthy to dull, sometimes sub-metallic if the limonite is dense.

  3. 3

    Texture

    Grain size and surface feel: coarse, fine, glassy

    Often earthy or powdery on the surface, but can be dense and compact internally. The external form will be that of pyrite crystals (cubes, pyritohedrons, octahedrons).

  4. 4

    Crystal Form

    Shape of visible crystals or crystal faces

    Retains the crystal habit of the original pyrite, most commonly cubes, pyritohedrons (a 12-faced form), or octahedrons. Striations may be visible on crystal faces, inherited from the original pyrite.

  5. 5

    Cleavage

    How it breaks: flat cleavage planes vs irregular fracture

    None, as limonite itself does not exhibit cleavage. The original pyrite's cleavage is not preserved.

  6. 6

    Geological Environment

    The rock formation and setting where it occurs

    Found in the oxidized zones (gossans) of sulfide ore deposits, in sedimentary rocks where pyrite has formed and subsequently oxidized, and in weathered igneous or metamorphic rocks containing pyrite. It is common in environments where pyrite has been exposed to surface or near-surface weathering processes.

Key Facts

Hardness
4 to 5.5 on the Mohs scale (for limonite, but can vary depending on density and purity)
Specific Gravity
2.7 to 4.3 (variable, depending on water content and density)
Crystal System
None (amorphous or cryptocrystalline for limonite itself, but the external form is isometric, inherited from pyrite)
Color
Yellowish-brown, reddish-brown, dark brown, blackish-brown
Luster
Earthy, dull, sometimes sub-metallic
Transparency
Opaque
Fracture
Conchoidal to uneven
Cleavage
None
Composition
Hydrated iron oxide (Fe2O3·nH2O), replacing iron sulfide (FeS2)

Physical characteristics

  • Crystal Habit: Pseudomorphic after pyrite, typically cubic, pyritohedral, or octahedral. May show striations inherited from pyrite.
  • Cleavage Type: None
  • Fracture Type: Conchoidal to uneven
  • Tenacity: Brittle
  • Luster Type: Earthy to dull

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