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Stilbite

Mineral

NaCa4(Si27Al9)O72·28H2O

Also known as: Stilbite-Ca, Stilbite-Na (though Stilbite-Ca is far more common and often simply referred to as Stilbite)

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Description

Stilbite is a tectosilicate mineral characterized by its distinctive sheaf-like or radiating crystal aggregates, often resembling bundles of wheat. It is a member of the zeolite group, known for its porous structure and ability to exchange ions and absorb water. The most common variety is Stilbite-Ca, which is calcium-rich. Stilbite-Na is a less common sodium-rich variety. It typically forms in the late stages of volcanic rock alteration, filling voids and fissures. Its delicate appearance and often vibrant colors make it a favorite among mineral enthusiasts.

How to Identify

Color
White, colorless, pale yellow, pink, salmon-orange, reddish-brown. Pink to salmon-orange are very characteristic.
Luster
Vitreous (glassy) to pearly on cleavage surfaces.
Texture
Often forms radiating, sheaf-like aggregates or tabular crystals. Can also be fibrous or granular.
Crystal Form
Monoclinic. Crystals are typically tabular, often forming characteristic 'sheaf-of-wheat' aggregates, divergent sprays, or bow-tie shapes. Individual crystals are often elongated along the c-axis.
Cleavage
Perfect on {010}, yielding pearly luster on this surface.
Geological Environment
Amygdaloidal cavities and fractures in basalt and other mafic volcanic rocks; hydrothermal veins; granite pegmatites; some metamorphic rocks.

Key Facts

  • Hardness: 3.5-4 on the Mohs scale
  • Specific Gravity: 2.12-2.22
  • Crystal System: Monoclinic
  • Color: White, colorless, pale yellow, pink, salmon-orange, reddish-brown
  • Luster: Vitreous to pearly
  • Transparency: Transparent to translucent
  • Fracture: Uneven
  • Cleavage: Perfect on {010}
  • Composition: Hydrous calcium sodium aluminum silicate

Quick Check

  • Color: White, pale yellow, pink, salmon-orange, reddish-brown
  • Luster: Vitreous to pearly
  • Streak: White

Physical Characteristics

  • Crystal Habit: Typically forms tabular crystals, often aggregated into characteristic 'sheaf-of-wheat' bundles, divergent sprays, or bow-tie shapes. Can also be fibrous, columnar, or granular.
  • Cleavage Type: Perfect on one plane ({010}), leading to a pearly luster on this surface.
  • Fracture Type: Uneven to subconchoidal.
  • Tenacity: Brittle.
  • Luster Type: Vitreous (glassy) on crystal faces, pearly on cleavage surfaces.

Formation

Stilbite is a hydrous calcium sodium aluminum silicate mineral belonging to the zeolite group. It typically forms as a secondary mineral in the amygdaloidal cavities and fractures of basaltic and other mafic volcanic rocks. It can also occur in hydrothermal veins, granite pegmatites, and some metamorphic rocks. Its formation is generally associated with low-temperature hydrothermal alteration processes, where circulating fluids interact with primary minerals, leading to the precipitation of zeolites.

Usage

Stilbite has limited industrial uses compared to some other zeolites. It is primarily a collector's mineral due to its attractive crystal forms and colors. Historically, zeolites, including stilbite, have been investigated for their ion-exchange properties, molecular sieving capabilities, and catalytic applications, though other zeolites are more commonly employed for these purposes. Its aesthetic appeal makes it popular in mineral collections and sometimes used in lapidary arts for decorative purposes.

Age Distribution

Stilbite forms in a variety of geological settings and is not restricted to a specific geological age. It is commonly found in Cenozoic and Mesozoic volcanic rocks, but can also occur in older metamorphic and sedimentary rocks.

Where to Find

Deccan Traps, India

World-renowned for producing exceptional specimens of stilbite, often associated with apophyllite, cavansite, and other zeolites in basaltic amygdales. Particularly famous localities include Nashik, Pune, and Mumbai.

Faroe Islands

Known for fine stilbite specimens, often in association with other zeolites in volcanic rocks.

Iceland

Abundant in basaltic lavas, forming excellent crystal aggregates in cavities.

Nova Scotia, Canada

Classic locality for zeolites, including stilbite, found in basalt flows along the Bay of Fundy.

Patterson, New Jersey, USA

Historic locality for zeolites, including stilbite, found in the basalt quarries.

Scotland, UK

Various localities, particularly on the Isle of Skye and other volcanic areas, yield stilbite.

Italy

Found in volcanic rocks, particularly in the Alps and other regions.

Finding Tips

Look in Volcanic Rocks

Stilbite is most commonly found in the amygdaloidal cavities (gas bubbles filled with secondary minerals) and fractures of basaltic and other mafic volcanic rocks. Search for areas with exposed lava flows.

Identify Associated Minerals

Stilbite often co-occurs with other zeolites (e.g., heulandite, apophyllite, cavansite, laumontite, scolecite) and calcite. The presence of these minerals can be a good indicator.

Observe Crystal Habit

Look for the characteristic 'sheaf-of-wheat' or radiating, divergent crystal aggregates. These forms are quite distinctive for stilbite.

Check for Pearly Luster

The perfect cleavage plane of stilbite often exhibits a pearly luster, which can help in identification.

Consider Color

While it can be white or colorless, the salmon-pink to orange-red hues are particularly characteristic and attractive.

Similar Rocks

Heulandite

(Ca,Na)2-3Al3(Al,Si)2Si13O36·12H2O

Also known as: Heulandite-Ca, Heulandite-Na, Heulandite-K, Heulandite-Sr

Laumontite

CaAl2Si4O12·4H2O

Also known as: Laumontite-Ca

Scolecite

CaAl2Si3O10·3H2O

Also known as: None

Mesolite

Na2Ca2Al6Si9O30·8H2O

Also known as: None

Scientific Classification

Mineral Class
Silicates
Group
Zeolite Group (Heulandite-Stilbite Series)
Crystal System
Monoclinic
Chemical Formula
NaCa4(Si27Al9)O72·28H2O (Stilbite-Ca, the most common variety, has a simplified formula of CaAl2Si7O18·7H2O, but the more precise formula reflects the Na substitution and full hydration)
Composition
Hydrous calcium sodium aluminum silicate. The ratio of Si to Al is typically 3:1, and the water content is significant.

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